You're unhappy with the situation... I'm not sure what difference it makes if it seems appropriate to anyone else. I'd be unhappy if I was married and my wife had some strange schedule for sex. I must have missed the relevance of the smoking.
If he really believes this 2 day recovery thing and won't listen to you then he probably isn't going to listen to a marriage counselor or therapist but it's worth a suggestion.
I don't think there are many posts here that are considered unworthy or too much information
I'm sorry if you got an anti-christian tag here for your other post but you shouldn't let that inhibit you. Good luck with working this out.