I especially liked Rickman in "Galaxy Quest." Not quite a villain, but nicely satirical.

Eta: I read an interview with some big actor once who said it was harder to play evil than to play good. Kind of like Tolstoy on families, if you know what I mean. Anyway I think Rickman is a good illustration of that.

Etaa: and if none of that makes sense, it's probably the whisk(e)y.